921229-22-3

Upstream product

• 626-95-9 1,4-Pentanediol 
• 921229-15-4 (2E)-ethyl 3-(2-(7-hydroxy-4-methylhept-3-enyl)phenyl)acrylate 
• 921229-11-0 C₃₅H₄₄O₃Si 
• 921229-01-8 2-[5-(tert-butyl-diphenyl-silanoxy)-pentane-2-sulfonyl]-benzothiazole 
• 944382-83-6 2-[4-(tert-butyldiphenyl-silanyloxy)-1-methyl-butylsulfanyl]-benzothiazole 
• 558465-78-4 (rac)-5-{[tert-butyl(diphenyl)silyl]oxy}pentan-2-ol 
• 921229-18-7 (2E)-ethyl 3-(2-(7-chloro-4-methylhept-3-enyl)phenyl)acrylate 

Downstream Products

• 921229-26-7 (2E)-3-(2-(7-chloro-4-methylhept-3-enyl)phenyl)acrylaldehyde 
• 921229-29-0 (1E)-1-(2-(7-chloro-4-methylhept-3-enyl)phenyl)pent-1-en-4-yn-3-ol 
• 921229-32-5 (1E)-1-(2-(7-chloro-4-methylhept-3-enyl)phenyl)pent-1-en-4-yn-3-one 
• 921229-34-7 (1E)-1-(2-(7-iodo-4-methylhept-3-enyl)phenyl)pent-1-en-4-yn-3-one 

Relevant academic research and scientific papers

Cascade radical-mediated cyclisations with conjugated ynone electrophores. An approach to the synthesis of steroids and other novel ring-fused polycyclic carbocycles

A cascade radical-mediated Diels-Alder reaction with the iododienynone 16b produced the tricyclic ketone 17 (22%). By contrast, treatment of the substituted furans 36 and 47 with Bu3SnH-AIBN, instead led to the tetracycles 44 and 58 respectivel

An attempted cascade radical-mediated cyclisation approach to ring-D aromatic steroids

A synthetic approach to ring-D aromatic steroids, viz. 5, based on a cascade of radical-mediated cyclisations from the ortho-aryl-substituted iododienynones 12 and 13, instead led to the macrocyclic ketone 16 or to the novel bridged tricycle 17, respectively, as the major products. Georg Thieme Verlag Stuttgart.