92168-48-4

Usage

InChI:InChI=1/C13H26N2O/c1-5-7-9-15(10-8-6-2)11-14-13(16)12(3)4/h3,5-11H2,1-2,4H3,(H,14,16)

Upstream product

• 80179-56-2 N,N-dibutylmethaniminium chloride 
• 79-39-0 Methacrylamide 
• 111-92-2 dibutylamine 
• 20280-10-8 N,N,N',N'-tetrabutylmethylenediamine 
• 67953-77-9 N-(hydroxymethyl)dibutylamine 

Relevant academic research and scientific papers

Synthesis of: N -[(dialkylamino)methyl]acrylamides and N -[(dialkylamino)methyl]methacrylamides from Schiff base salts: Useful building blocks for smart polymers

The traditional thermal Mannich reaction is unsuitable for preparing polymerizable N-methylene amino substituted acrylamides and methacrylamides. Herein we provide a facile multi-gram high yield synthesis of these monomeric precursors to stimuli-responsive polymers by the addition of acrylamides and methacrylamides onto in situ generated or freshly isolated methylene Schiff base (iminium) salts. The X-ray crystal structure of the hydrated iminium salt, 1-(hydroxymethyl)azocan-1-ium chloride and monomer·HCl salt (N-[(azocan-1-yl)methyl]prop-2-enamide hydrochloride) is described.

Synthesis of N-(Dialkylaminomethyl)(meth)acrylamides by the Mannich Reaction in Aqueous Solutions

Synthesis of N-(dialkylaminomethyl)(meth)acrylamides from (meth)acrylamide, formaldehyde, and dialkylamines in aqueous solutions was studied. The features of the main and side reactions were examined. Conditions were found for formation of target products with the yield and selectivity close to 100 percent.