92232-46-7

Upstream product

• 82707-04-8 methyl 3-O-benzyl-6-O-t-butyldiphenylsilyl 2,4-dideoxy-2,4-di-C-methyl-α-D-gulopyranoside 
• 75-08-1 ethanethiol 
• 82731-53-1 (2S,4R,5R,6S)-2-Hydroxymethyl-6-methoxy-3,5-dimethyl-tetrahydro-pyran-4-ol 
• 100-39-0 benzyl bromide 

Downstream Products

• 92232-47-8 (3R,4R,5R,6S)-4-Benzyloxy-6-(tert-butyl-diphenyl-silanyloxymethyl)-3,5-dimethyl-tetrahydro-pyran-2-ol 
• 92232-49-0 3-O-benzyl-2,4-dideoxy-2,4-di-C-methyl-5-O-methylsulfonyl-1-O-triphenylmethyl-D-gulitol 
• 92232-50-3 5,6-anhydro-3-O-benzyl-2,4-dideoxy-2,4-di-C-methyl-1-O-triphenylmethyl-L-galactitol 

Relevant academic research and scientific papers

ASSEMBLY OF THE C19-C29 ALIPHATIC SEGMENT OF RIFAMYCIN S FROM D-DLUCOSE BY THE CHIRON APPROACH

We describe a stereocontrolled method for the construction of the aliphatic chain of rifamycin S, based on a strategy that utilizes carbohydrates as optically active precursors.