92234-03-2

Basic information

• Product Name: 2-Ethoxy-3-phenyl-2,3-bis-trimethylsilanyloxy-propionic acid ethyl ester
• Synonyms: 2-Ethoxy-3-phenyl-2,3-bis-trimethylsilanyloxy-propionic acid ethyl ester
• CAS NO: 92234-03-2
• Molecular Weight: 398.647
• Mol File: 92234-03-2.mol

Chemical Properties

• CAS DataBase Reference: 2-Ethoxy-3-phenyl-2,3-bis-trimethylsilanyloxy-propionic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Ethoxy-3-phenyl-2,3-bis-trimethylsilanyloxy-propionic acid ethyl ester(92234-03-2)
• EPA Substance Registry System: 2-Ethoxy-3-phenyl-2,3-bis-trimethylsilanyloxy-propionic acid ethyl ester(92234-03-2)

Safety Data

• Hazardous Substances Data: 92234-03-2(Hazardous Substances Data)

Upstream product

• 90054-58-3 1,2-diethoxy-1,2-bis(trimethylsilyloxy)ethylene 
• 100-52-7 benzaldehyde 
• 31502-12-2 (E)-1,2-Diethoxy-1,2-bis-trimethylsilanyloxy-ethene 

Relevant articles and documents

RHODIUM-DIPHOSPHINE COMPLEXES AS CATALYSTS IN ALDOL ADDITIONS

Rhodium(I)-diphosphine complexes catalyze the aldol addition of enolsilanes to aldehydes, an enantioselective version being possible if chiral phosphines are used.

A MILD AND VARIABLE SYNTHESIS OF α-KETOESTERS

The ZnCl2 promoted addition of 1,2-diethoxy-1,2-disilyloxyethylene 1 with electrophiles such as aldehydes, ketones, α,β-unsaturated ketones or tertiary alkyl halides allows for a simple synthesis of α-ketoesters.