92248-91-4

Basic information

• Product Name: cis-5-methylcyclohex-2-en-1-ol 4-nitrobenzoate
• Synonyms: cis-5-methylcyclohex-2-en-1-ol 4-nitrobenzoate
• CAS NO: 92248-91-4
• Molecular Weight: 261.277
• Mol File: 92248-91-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: cis-5-methylcyclohex-2-en-1-ol 4-nitrobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: cis-5-methylcyclohex-2-en-1-ol 4-nitrobenzoate(92248-91-4)
• EPA Substance Registry System: cis-5-methylcyclohex-2-en-1-ol 4-nitrobenzoate(92248-91-4)

Safety Data

• Hazardous Substances Data: 92248-91-4(Hazardous Substances Data)

Upstream product

• 7214-50-8 5-methylcyclohex-2-en-1-one 
• 122-04-3 4-nitro-benzoyl chloride 
• 3718-55-6 5-methyl-2-cyclohexen-1-ol 

Downstream Products

• 122-04-3 4-nitro-benzoyl chloride 
• 3718-55-6 trans-5-methyl-2-cyclohexen-1-one 
• 22049-46-3 (±)-cis-5-methyl-2-cyclohexenol 

Relevant articles and documents

Palladium-Catalyzed C-Alkylations of the Highly Acidic and Enolic Triacetic Acid Lactone. Mechanism and Stereochemistry

4-Hydroxy-6-methyl-2-pyrone (triacetic acid lactone) (1) is efficiently alkylated at C-3 with primary and secondary allylic substrates under thermodynamic control by using palladium(0) catalysts.Controlled hydrogenation of the resulting allylated derivatives affords pyrones with saturated chains at C-3.Allylic alkylations occur with retention of configuration at the allylic center, probably through a reversible kinetically favored O-alkylation.