92254-94-9

Upstream product

• 77929-81-8 Phenylphosphonsaeure-chlorid-p-toluidid 
• 124-41-4 sodium methylate 
• 824-72-6 P,P-dichlorophenylphosphine oxide 
• 5720-05-8 4-methylphenylboronic acid 
• 40334-32-5 P-phenyl-P-methoxy phosphinamide 
• 26926-25-0 ethyl (4-methylphenyl)phenylphosphinate 
• 100926-10-1 N-hydroxylamine 
• 106-49-0 p-toluidine 
• 100926-15-6 C₁₄H₁₆NO₄PS 
• 57906-78-2 p-Tolyl-phenyl-phosphinigsaeurechlorid 
• 13118-96-2 phenyl-p-tolyl-phosphinic acid 
• 106-38-7 para-bromotoluene 

Relevant academic research and scientific papers

The Chan-Evans-Lam N-arylation of phosphonic/phosphinic amides

A stoichiometric copper(II)-mediated arylation protocol of phosphinamides and phosphonamides was herein demonstrated. Various unreported N-aryl phosphinamides and phosphonamides were successfully prepared through Chan-Evans-Lam reaction with high efficiency (up to 88% yields) and good functional groups tolerance (30 examples) in the absence of any ligands or co-catalysts.

N-hydroxylamines: Influence of Substituents on the Competitive Migration of Aryl and Phenyl Groups in the Lossen-like Rearrangement of their O-Methanesulphonyl Derivatives

The N-hydroxylamines ArPhP(O)NHOH (4) (Ar=p-XC6H4; X=MeO, Me, Cl, NO2) have been prepared from the corresponding phosphinic chlorides (3) using O-(trimethylsilyl)hydroxylamine and converted into the O-methanesulphonyl derivatives