92297-10-4Relevant academic research and scientific papers
Stereoselective synthesis of (7aS)-1-methylenehexahydro-1H-pyrrolizine and (-)-heliotridane from N-diphenylmethyl-(S)-proline ethyl ester
Lysenko,Kulinkovich
, p. 70 - 74 (2007/10/03)
Alkaloid (7aS)-1-methylenehexahydro-1H-pyrrolizine was synthesized from N-diphenylmethyl-(S)-proline ethyl ester by cyclopropanation of the ester group with ethylmagnesium bromide in the presence of titanium tetraisopropoxide, replacement of the protectin
