92339-58-7Relevant academic research and scientific papers
Phenylthionitromethane: a Versatile Reagent for the Conversion of Aldehydes into α-Substituted S-Phenyl Thioesters
Banks, Bernard J.,Barrett, Anthony G. M.,Russell, Mark A.
, p. 670 - 671 (1984)
Acetaldehyde and isobutyraldehyde, RCHO, reacted with phenylthionitromethane (KOH, MeOH) followed by methanesulphonyl chloride (Et3N, CH2Cl2) to give the alkenes, RCH=C(SPh)NO2; these reacted with the nucleophiles i, potassium
Preparation and Synthetic Utility of 1-Phenylthio-1-nitro Epoxides. Facile Preparation of α-Substituted S-Phenyl Thio esters
Ashwell, Mark,Jackson, Richard F. W.
, p. 282 - 283 (2007/10/02)
Novel 1-Phenylthio-1-nitro epoxides (2), readily prepared by epoxidation of the corresponding 1-phenylthio-1-nitroalkenes (1), react efficiently under mild conditions with a variety with a variety of hetero nucleophiles to give α-substituted S-phenyl thio
Preparation of α-Substituted S-Phenyl Thio Esters from Aldehydes and (Phenylthio)nitromethane
Barrett, Anthony G. M.,Graboski, Gregory, G.,Russell, Mark A.
, p. 1012 - 1015 (2007/10/02)
Acetaldehyde and isobutyraldehyde, RCHO, reacted with (phenylthio)nitromethane (KO-t-Bu, THF, t-BuOH) followed by methanesulfonyl chloride (Et3N, CH2Cl2) to give the (Z)-alkenes RCH=C(SPh)NO2.These reacted with the nucleophiles NuM = potassium phthalimid
