923933-86-2Relevant academic research and scientific papers
Synthesis of 1,1'-ferrocenediyl salicylaldimine ligands and their application in titanium-initiated lactide polymerization
Atkinson, Robert C. J.,Gerry, Kathryn,Gibson, Vernon C.,Long, Nicholas J.,Marshall, Edward L.,West, Lara J.
, p. 316 - 320 (2008/10/09)
The synthesis of bidentate N/O 1,1'-ferrocenediyl analogues of N-aryl-salicylaldimines has been accomplished from the previously unreported 1'-hydroxyferrocenecarbaldehyde, 3. Thus, the reaction of 3 with 2,6-diisopropylaniline and with aniline leads to the isolation of N-(2,6-diisopropylphenyl)-(1'(hydroxy)ferrocenyl)aldimine, 5, and N-phenyl-(1'-(hydroxy)ferrocenyl)aldimine, 6, respectively. However, attempts to synthesize analogues of bis(iminophenoxide) (salen) ligands by treatment of 3 with 1,2-ethylenediamine and with trans-(+/-)-1,2-diaminocyclohexane led to intractable product mixtures, while reaction with 1,2-phenylenediamine resulted in formation of a substituted benzimidazole. Titanium bis(isopropoxide) complexes of 5,6, and, for comparative purposes, 1'-(diphenylphosphino) hydroxyferrocene have been synthesized, and in a preliminary study all three complexes were found to initiate the ring-opening polymerization of rac-lactide in a well-controlled manner.
