92414-07-8Relevant academic research and scientific papers
α-selective ribofuranosylation of alcohols with ribofuranosyl iodides and triphenylphosphine oxide
Oka, Natsuhisa,Kajino, Rin,Takeuchi, Kaoru,Nagakawa, Haruna,Ando, Kaori
, p. 7656 - 7664 (2014/10/15)
Ribofuranosylation of a variety of alcohols with ribofuranosyl iodides in the presence of a base and triphenylphosphine oxide afforded the corresponding α-ribofuranosides with diastereoselectivities ≥ 99:1. This reaction can be carried out under mildly basic conditions and is thus compatible with acid-sensitive functional groups.
Dehydrative glycosylation of tri-O-benzylated 1-hydroxyribofuranose catalyzed by a copper(II) complex
Suzuki, Takeyuki,Watanabe, Shoko,Yamada, Taichiro,Hiroi, Kunio
, p. 2561 - 2563 (2007/10/03)
A phosphine/Cu(II) complex catalyzes the dehydrative glycosylation of tri-O-benzylated 1-hydroxyribofuranose to give the ribofuranoside with high stereoselectivity.
A FACILE SYNTHESIS OF α-GLUCOSIDES AND α-RIBOSIDES FROM THE CORRESPONDING 1-O-ACYL SUGARS AND ALCOHOLS IN THE PRESENCE OF TRITYL PERCHLORATE
Mukaiyama, Teruaki,Kobayashi, Shu,Shoda, Shin-ichiro
, p. 907 - 910 (2007/10/02)
In the presence of trityl perchlorate, 1-O-bromoacety-β-D-glucose stereoselectively reacts with alcohols to give the corresponding α-glucosides in good yields.The similar reaction of 1-O-acetyl-β-D-ribose affords the corresponding β-ribosides exclusively,
