92484-70-3Relevant academic research and scientific papers
APPLICATION OF THE INTRAMOLECULAR MAGNESIUM-ENE REACTION TO THE STEREOCONTROLLED TOTAL SYNTHESES OF (+/-)-12-ACETOXYSINULARENE AND (+/-)-5-EPI-12-ACETOXYSINULARENE
Oppolzer, Wolfgang,Begley, Tadhg,Ashcroft, Alison
, p. 825 - 828 (1984)
The sesquiterpene (+/-)-12-acetoxysinularene (1) and its C(5)-epimer 13 were each synthesized stereoselectively from the norbornyl-iodoacetal 7 in 5percent and 7percent overall yields.The critical step 10 11 involves the regio- and stereoselective "ma
