APPLICATION OF THE INTRAMOLECULAR MAGNESIUM-ENE REACTION TO THE STEREOCONTROLLED TOTAL SYNTHESES OF (+/-)-12-ACETOXYSINULARENE AND (+/-)-5-EPI-12-ACETOXYSINULARENE

DOI: 10.1016/S0040-4039(01)80037-X

Source and publish data:

Tetrahedron Letters p. 825 - 828 (1984)

Update date:2022-08-04

Topics:

Authors:

Oppolzer, Wolfgang

Begley, Tadhg

Ashcroft, Alison

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Article abstract of DOI:10.1016/S0040-4039(01)80037-X

The sesquiterpene (+/-)-12-acetoxysinularene (1) and its C(5)-epimer 13 were each synthesized stereoselectively from the norbornyl-iodoacetal 7 in 5percent and 7percent overall yields.The critical step 10 <*> 11 involves the regio- and stereoselective "ma

Full text of DOI:10.1016/S0040-4039(01)80037-X

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