925-69-9Relevant academic research and scientific papers
Model sensory compounds (by machine translation)
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Paragraph 0047-0049, (2019/02/04)
The present invention relates to novel compounds and their use as a flavoring material. (by machine translation)
FLAVOR AND FRAGRANCE FORMULATION (I)
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Paragraph 0071, (2015/11/16)
The present invention relates to the use of specific organic compounds as flavor and fragrance material. Furthermore the invention relates to new specific organic compounds and their synthesis, as well to flavor and fragrance formulations comprising at least one of the specific organic compounds.
Synthesis of Phytone and Phytol through Prins Reaction of Norphytene and its Isomer
Kamath, S. V.,Rangaishenvi, M. V.,Phadke, A. S.,Kulkarni, Sheshgiri N.
, p. 1008 - 1009 (2007/10/02)
Prins reaction on 2,6-dimethyloct-2-ene (IIa) using paraformaldehyde furnishes 2-isopropenyl-5-methylheptanol (IIIa) which on periodate oxidation or ozonolysis followed by Jones' oxidation gives the acid (Va).The latter (Va) upon pyrolysis affords 6-methyl-2-octanone (VIa).Similarly, norphytene isomer (IIb) furnishes phytone (VIb) through IIIb, IVb and Vb.Norphytene (Ib) on Prins reaction gives mainly E-phytol as one of the products.
1,5-ADDITION OF DIALKYLCUPRATE REAGENTS TO ALKYLCYCLOPROPYL KETONES
Mioskowski, Charles,Manna, S.,Falck, J. R.
, p. 5521 - 5524 (2007/10/02)
Cyclopropyl ketones undergo 1,5-addition at the less substituted carbon using the complex reagent R2CuCNLi2*BF3.
