925458-13-5

Upstream product

• 693-02-7 hex-1-yne 
• 156715-27-4 (R)-(-)-4-Nonin-2-ol 
• 156647-91-5 (R)-(-)-8-Nonin-2-ol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 866423-19-0 (2R,3S,9R)-9-(tert-Butyl-diphenyl-silanyloxy)-2,3-dihydroxy-decanoic acid ethyl ester 
• 866423-21-4 {(4S,5S)-5-[(R)-6-(tert-butyldiphenylsilyloxy)heptyl]-2,2-dimethyl-1,3-dioxolan-4-yl}methanol 
• 925458-11-3 (4S,5S)-5-[(R)-6-(tert-butyldiphenylsilyloxy)heptyl]-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde 
• 866423-16-7 (7-benzyloxy-1-methyl-heptyloxy)-tert-butyl-diphenyl-silane 
• 866423-18-9 (E)-(R)-9-(tert-Butyl-diphenyl-silanyloxy)-dec-2-enoic acid ethyl ester 
• 866423-15-6 (R)-8-Benzyloxy-octan-2-ol 
• 925458-12-4 (Z)-methyl 3-{(4S,5S)-5-[(R)-6-(tert-butyldiphenylsilyloxy)hept-1-enyl]-2,2-dimethyl-1,3-dioxolan-4-yl}acrylate 
• 866423-22-5 (Z)-3-{(4S,5S)-5-[(R)-6-(tert-Butyl-diphenyl-silanyloxy)-heptyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-acrylic acid ethyl ester 
• 866423-20-3 (4R,5S)-5-[(R)-6-(tert-Butyl-diphenyl-silanyloxy)-heptyl]-2,2-dimethyl-[1,3]dioxolane-4-carboxylic acid ethyl ester 

Downstream Products

• 851616-13-2 cladospolide B 

Relevant academic research and scientific papers

Alkyne-mediated approach for total syntheses of cladospolides A, B, C and iso-cladospolide B

A general strategy for the stereoselective total syntheses of cladospolides A, B, and C and iso-cladospolide B has been accomplished. The key steps provide easy access to the target molecules and include an alkyne-zipper reaction, a Sharpless asymmetric e

Stereoselective total synthesis of iso-cladospolide B

A simple and efficient stereoselective total synthesis of iso-cladospolide B and a formal total synthesis of cladospolide B, using Jacobsen's hydrolytic kinetic resolution, is described. Georg Thieme Verlag Stuttgart.

Efficient total synthesis of iso-cladospolide B and cladospolide B

An efficient synthesis of iso-cladospolide B and cladospolide B has been achieved using Jacobsen's hydrolytic kinetic resolution (HKR), Sharpless asymmetric dihydroxylation and Yamaguchi macrolactonization as the key steps.