92562-99-7

Upstream product

• 92541-15-6 6-(2-Benzyloxy-3,4-dimethoxy-phenyl)-4-(1-hydroxy-ethyl)-7-methyl-pyrrolo[3,4-c]pyridine-1,3-dione 
• 92541-05-4 (Z)-3-Amino-1-(2-benzyloxy-3,4-dimethoxy-phenyl)-2-methyl-but-2-en-1-one 
• 92541-06-5 2-(2-Benzyloxy-3,4-dimethoxy-phenyl)-3,4,7-trimethyl-7H-furo[3,4-b]pyridin-5-one 
• 92541-07-6 2-(2-Benzyloxy-3,4-dimethoxy-phenyl)-3,7-dimethyl-5-oxo-5,7-dihydro-furo[3,4-b]pyridine-4-carbaldehyde 
• 92562-97-5 2-(2-Benzyloxy-3,4-dimethoxy-phenyl)-3,7-dimethyl-5-oxo-5,7-dihydro-furo[3,4-b]pyridine-4-carboxylic acid 
• 92541-14-5 2-(2-Benzyloxy-3,4-dimethoxy-phenyl)-3,7-dimethyl-5-oxo-5,7-dihydro-furo[3,4-b]pyridine-4-carboxylic acid amide 
• 5457-19-2 5-methyltetronic acid 

Relevant academic research and scientific papers

AN UNUSUAL REARRANGEMENT DURING PYRIDINE SYNTHESIS. ANOMALOUS CONDENSATION OF A β-KETO ENAMINE WITH A TETRONIC ACID.

The condensation of a β-keto enamine 1 with 5-methyltetronic acid takes an anomalous course.Single crystal X-ray analysis and chemical evidence establish the rearranged pyridine structure 15 for this condensation product.