92567-60-7

Upstream product

• 92567-59-4 2,3,4,6-tetra-O-benzyl-1-C-(4-hydroxy-1-Z-butenyl)-D-glucopyranose 
• 92621-59-5 (3S,4S,5R)-tribenzyloxy-(2R)-benzyloxymethyl-1,7-dioxa-(6S)-spiro<5,5>undec-10-ene 
• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 
• 166828-15-5 4,5,6,8-tetra-O-benzyl-1,2-dideoxy-α-D-gluco-oct-1-eno-3-ulopyranose 
• 13096-62-3 (3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-one 
• 213776-91-1 3-buten-1-yl (4,5,6,8-tetra-O-benzyl-1,2-dideoxy)-α-D-gluco-oct-1-eno-3-ulopyranoside 
• 100-39-0 benzyl bromide 
• 92567-63-0 (3S,4S,5R)-trihydroxy-(2R)-hydroxymethyl-1,7-dioxa-(6R)-spiro<5,5>undec-10-ene 

Downstream Products

• 92567-61-8 (3S,4S,5R)-tribenzyloxy-(2R)-benzyloxymethyl-1,7-dioxa-(6R)-spiro[5,5]undecane 

Relevant academic research and scientific papers

Synthesis and elaboration of functionalised carbohydrate-derived spiroketals

The scope of a stereoselective three-step approach for the synthesis of sugar derived spiroketals is presented. The methodology consists of Grignard addition of vinyl- or allylmagnesium bromide to a carbohydrate lactone, followed by K-10 clay mediated gly

A novel and flexible synthesis of pyranose spiroacetal derivatives

A three-step approach to chiral pyranose [5,4], [5,5], [5,6] and [5,7] unsaturated spiroacetal derivatives from perbenzylated glucopyranolactone 1 is presented. The strategy involves Grignard addition of vinyl or allyl magnesium bromide to 1 to give 2 and

SYNTHESIS OF A CHIRAL 1,7-DIOXASPIROUNDECENE. A MODEL FOR THE SPIROACETAL SUBUNIT OF AVERMECTIN B1a

The stereocontrolled synthesis of a chiral, polyhydroxy 1,7-dioxaspiroundecene from D-glucose is described.The bicyclic system with a different pattern of substitution can be found in a number of biologically important natural products such as the avermectins and the milbemycins.