92583-51-2Relevant academic research and scientific papers
NITRONE CYCLOADDITIONS WITH VINYL SILANES: THE TOTAL SYNTHESIS OF DEOXYSUGARS.
DeShong, Philip,Leginus, Joseph M.
, p. 5355 - 5358 (1984)
The total synthesis of (+/-)-rhodinose (2) and benzoxocin 4, a model system for the glycosidic moiety of nogalomycin, are reported.The key transformation in each reaction sequence involves the cycloaddition of a nitrone with vinyltrimethylsilane to produc
