926033-46-7Relevant academic research and scientific papers
Highly regio- and stereoselective diels-alder cycloaddition of difluoro(methylene)cyclopropanes
Hang, Xiao-Chun,Chen, Qing-Yun,Xiao, Ji-Chang
experimental part, p. 1101 - 1106 (2009/04/05)
The Diels-Alder reactions of difluoro(methylene)cyclopropanes (F 2MCPs) with cyclic dienes are described. These cycloaddition reactions exhibited complete regioselectivity and high endo-stereoselectivity. The obtained cycloadducts underwent a retro-Diels-Alder reaction to give the original dienophiles and dienes when heated, reflecting the reversible Diels-Alder reactivity of F2MCPs. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.
