92617-92-0Relevant articles and documents
INTRAMOLECULAR NUCLEOPHILIC ADDITION OF PHENOLATE TO UNACTIVATED DOUBLE AND TRIPLE BONDS. RELATIVE REACTIVITY, REGIOSPECIFICITY, STEREOCHEMISTRY, AND MECHANISM
Evans, Christopher M.,Kirby, Anthony J.
, p. 1269 - 1276 (2007/10/02)
The intramolecular nucleophilic addition of phenolate oxygen to the unactivated triple bond of a series of terminal acetylenes (11) is a two-step process, involving rate-determining formation of a vinyl carbanion.Reaction is almost 104 times fa