92638-81-8Relevant articles and documents
Synthesis of Benzo[b]fluoranthenes and Spiroacridines from Fluorene-Derived Alkenes and N-Arylimines via a Tandem Reaction with Benzynes
Wang, Weihua,Wan, Hongwei,Du, Guangfen,Dai, Bin,He, Lin
, p. 3496 - 3500 (2019)
Two tandem processes involving the cycloaddition of benzynes have been developed for the synthesis of polyaromatic hydrocarbons. Benzynes react with fluorene-derived alkenes through a tandem Diels-Alder reaction/dehydrogenation process to afford benzo[b]f
Synthesis method and application of spiro-substituted acridine compound
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Paragraph 0055-0062, (2021/07/17)
The invention relates to the technical field of preparation of organic photoelectric materials, in particular to a synthesis method and application of a spiro-substituted acridine compound. The synthesis method of the spiro-substituted acridine compound p
Deep-blue thermally activated delayed fluorescence emitters containing diphenyl sulfone group for organic light emitting diodes
Lee, In Hye,Kim, Ki Ju,Kim, Young Kwan,Kim, Young Sik,Shin, Dong Myung
, p. 4583 - 4589 (2019/05/08)
Novel blue thermally activated delayed fluorescence (TADF) emitters, D1-DPS and D2-DPS, were designed and synthesized. Diphenyl sulfone (DPS) group functioned as a common acceptor, and it combined with each of two different spiro-acridine groups, D1 and D2. The calculated energy differences (ΔEST) of the singlet and triplet excited states of D1-DPS (0.062 eV) and D2-DPS (0.128 eV) had sufficiently small AEST values, which is favorable in the thermally activated reverse intersystem crossing (RISC) process from the T1 state to the S1 state. A device doped 10 wt% of D2-DPS with ADN host material, obtained 5.05% of external quantum efficiency with deep-blue emission having CIExy coordinates of (0.152, 0.065). The results showed that these molecules are promising host-free TADF deep-blue emitters by inhibiting concentration quenching.