92669-96-0Relevant academic research and scientific papers
Catalytic enantioselective arylation of glyoxylate with arylsilanes: Practical synthesis of optically active mandelic acid derivatives
Aikawa, Kohsuke,Hioki, Yueta,Mikami, Koichi
supporting information; experimental part, p. 2346 - 2350 (2011/06/26)
Just a little does the trick! The catalytic enantioselective arylation using chiral dicationic palladium complexes provides a reliable and useful access to enantiomerically enriched mandelic-acid derivatives. Significantly low catalyst loading (down to 0.002 mol%) as well as easy catalyst handling are the advantage of this practical method.
Dilithiation of Aromatic Ethers
Crowther, G. P.,Sundberg, Richard J.,Sarpeshkar, Ashok M.
, p. 4657 - 4663 (2007/10/02)
The lithiations of anisole and all the isomeric dimethoxy- and trimethoxybenzenes with 2-5 equiv of n-butyllithium/TMEDA complex have been investigated under a variety of reaction conditions.Anisole and m-dimethoxybenzene do not undergo dilithiatian, but
