92669-98-2Relevant articles and documents
Metalation in hydrocarbon solvents: The mechanistic aspects of substrate-promoted ortho-metalations
Slocum,Dumbris, Seth,Brown, Scott,Jackson, Gina,LaMastus, Roslyn,Mullins, Elwood,Ray, Jonathan,Shelton, Phillip,Walstrom, Amy,Wilcox, J. Micah,Holman
, p. 8275 - 8284 (2003)
The methoxy-substituted aromatic reagents 1,2- and 1,3-dimethoxybenzene (1,2-DMB and 1,3-DMB) and 1,2,4-trimethoxybenzene (1,2,4-TMB) each undergo directed ortho-metalation in high yield in n-BuLi/hydrocarbon media without the aid of a catalyst. These rea
Preparation method of 2-methoxy-5-geranyl p-benzoquinone derivate and Scabellone B
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Paragraph 0049-0050, (2017/09/01)
The invention discloses a preparation method of a 2-methoxy-5-geranyl p-benzoquinone derivate. The method comprises the following steps: 1, preparing an intermediate product 1,2,4-trimethoxy-3-trimethylsilyl-benzene; 2, preparing an intermediate product 1
Preparation methods of 2-methoxyl-5-geranyl-p-benzoquinone derivative and Scabellone C
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Paragraph 0054; 0058; 0062; 0066; 0070; 0074; 0078, (2017/09/01)
The invention discloses a preparation method of a 2-methoxyl-5-geranyl p-benzoquinone derivative. The method is implemented by the following steps: 1, preparing a middle product 1,2,4-trimethoxy-3-trimethylsilyl-benzene; 2, preparing a middle product 1,2,
