92686-68-5Relevant academic research and scientific papers
ADDITION REACTIONS OF CYCLOOCTATETRAENE WITH 1,3-DIPHENYLISOBENZOFURAN THE BENZENE RING AS DIENOPHILE IN A CYCLOADDITION REACTION
Saito, Katsuhiro,Omura, Yoichi,Maekawa, Etsuro,Gassman, Paul G.
, p. 2573 - 2576 (1984)
Addition reactions of cyclooctatetraene with 1,3-diphenylisobenzofuran resulted in the formation of three 1:1 cycloadducts, 1,2, and 3, and a 1:2 cycloadduct, 4.Single crystal X-ray analysis established 3 to be a cage compound formed by an unprecedented cycloaddition reaction of 1 in which the double bond of the benzene moiety acted as the dienophile.
The addition of 1,3-diphenylisobenzofuran to cyclooctateraene and to dimethyl cyclooctatetraene-1,2-dicarboxylate. The benzene ring as a dienophile in an intramolecular diels-alder reaction
Saito,Omura,Maekawa,Gassman
, p. 395 - 400 (2007/10/02)
The reaction of cyclooctatetraene with 1,3-diphenylisobenzofuran afforded two kinds of 1:1 [2π+4π]-cycloadducts, a cage-type 1:1 cycloadduct and two classes of 1:2 cycloadducts. The cage-type compound was formed from one of the [2π+4π]-cycloadducts via an unprecedented second [2π+4π]-cycloaddition reaction in which the double bond of the benzene moiety acted as a dienophile. A similar reaction with dimethyl cyclooctatetraene-1,2-dicarboxylate gave a 1:1 [2π+4π]-cycloadduct and a 1:2 cycloadduct. No cage-type compound was formed.
