
Tetrahedron Letters p. 2573 - 2576 (1984)
Update date:2022-07-30
Topics:
Saito, Katsuhiro
Omura, Yoichi
Maekawa, Etsuro
Gassman, Paul G.
Addition reactions of cyclooctatetraene with 1,3-diphenylisobenzofuran resulted in the formation of three 1:1 cycloadducts, 1,2, and 3, and a 1:2 cycloadduct, 4.Single crystal X-ray analysis established 3 to be a cage compound formed by an unprecedented <4+2> cycloaddition reaction of 1 in which the double bond of the benzene moiety acted as the dienophile.
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(1984)