926907-29-1

Basic information

• Product Name: Benzenemethanol, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3,5-dimethoxy-a-methyl-
• CAS NO: 926907-29-1
• Molecular Formula: C16H28O4Si
• Molecular Weight: 312.481
• Mol File: 926907-29-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3,5-dimethoxy-a-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3,5-dimethoxy-a-methyl-(926907-29-1)
• EPA Substance Registry System: Benzenemethanol, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3,5-dimethoxy-a-methyl-(926907-29-1)

Safety Data

• Hazardous Substances Data: 926907-29-1(Hazardous Substances Data)

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 134-96-3 syringic aldehyde 
• 917-54-4 methyllithium 
• 106852-80-6 4-(t-butyldimethylsilyloxy)-3,5-dimethoxybenzaldehyde 

Downstream Products

• 2478-38-8 1-(4-hydroxy-3,5-dimethoxy-phenyl)-ethanone 
• 383176-01-0 methyl 4-O-tert-butyldimethylsilyl-3,5-dimethoxybenzoate 
• 926907-24-6 methanesulfonic acid 2,6-dimethoxy-4-[5-methoxy-7-(2-methyl-[1,3]dioxolan-2-yl)-3-methylene-2,3-dihydro-benzo[1,4]dioxin-2-yl]-phenyl ester 
• 926907-26-8 methanesulfonic acid 4-(7-acetyl-3-hydroxy-5-methoxy-3-methyl-2,3-dihydro-benzo[1,4]dioxin-2-yl)-2,6-dimethoxy-phenyl ester 

Relevant articles and documents

Inverse electron demand hetero-Diels-Alder reaction in preparing 1,4-benzodioxin from o-quinone and enamine

A process for synthesizing 1,4-benzodioxin, through oxidation of a phenol to an o-quinone followed by treatment with an enamine, has been developed. Adduct stereochemistry is found to be retained via this one-pot reaction. The method uses hypervalent iodine reagent under mild conditions and is compatible with a wide scope of phenols and enamines.