92739-64-5

Basic information

• Product Name: MESO-TETRA(4-N,N,N-TRIMETHYLANILINIUM) PORPHINE TETRACHLORIDE
• Synonyms: MESO-TETRA(4-N,N,N-TRIMETHYLANILINIUM) PORPHINE TETRACHLORIDE;5,10,15,20-TETRAKIS(4-TRIMETHYLAMMONIOPHENYL) PORPHINE TETRACHLORIDE
• CAS NO: 92739-64-5
• Molecular Formula: C₅₆H₆₂N₈*4Cl
• Molecular Weight: 988.96
• Product Categories: Porphyrins
• Mol File: 92739-64-5.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: MESO-TETRA(4-N,N,N-TRIMETHYLANILINIUM) PORPHINE TETRACHLORIDE(CAS DataBase Reference)
• NIST Chemistry Reference: MESO-TETRA(4-N,N,N-TRIMETHYLANILINIUM) PORPHINE TETRACHLORIDE(92739-64-5)
• EPA Substance Registry System: MESO-TETRA(4-N,N,N-TRIMETHYLANILINIUM) PORPHINE TETRACHLORIDE(92739-64-5)

Safety Data

• Hazardous Substances Data: 92739-64-5(Hazardous Substances Data)

Upstream product

• 80-48-8 methyl p-toluene sulfonate 
• 14945-24-5 N,N-dimethyl-4-[(5,10′,14′′,19′′′ )-10,15,20-tris(4-dimethylaminophenyl)-21,23-dihydroporphyrin-5-yl]aniline 

Downstream Products

• 96091-17-7 Fe(5,10,15,20-tetrakis(N,N,N-trimethylanilinium-4-yl)porphyrinate)⁽⁵⁺⁾ 

Relevant articles and documents

Cationic Porphyrins in Water. 1H NMR and Fluorescence Studies on Dimer and Molecular Complex Formation

Three kinds od cationic porphyrins have been employed to study intermolecular interaction of these porphyrins in water.Fluorescence behavior of 4,4',4",4'"-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis tetrachloride (TOPyP) is essentially the same as that of 4,4',4",4'"-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis tetrachloride (TMPyP), which has been assumed to form a dimer in water even at very low concentrations (>2 x 10-7 M).In contrast with these cationic porphyrins, 4,4',4",4'"-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis tetrachloride (TAPP) shows the fluorescence spectrum having well-resolved Q(0-0) and Q(0-1) bands.The self-association of TAPP is detectable at higher TAPP concentrations and/ or in the presence of NaCl. 1H NMR clearly indicates the formation of the TAPP aggregates where the monomer-aggregates exchange rates are fast.TMPyP and TOPyP form molecular complexes with proflavin (PFl) that are more stable than the TAPP-PFl complex.The continous variation method for the absorption spectral change indicates the 2:1 complex of TMPyP and/ or TOPyP and PFl and the 1:1 complex of TAPP and PFl.These cationic porphyrins also form molecular complexes with bovine serum albumin (BSA) at pH 5.3, the stoichiometries being 4:1 and 2:1 for the TMPyP- and TAPP-BSA complexes, respectively.All the experimental results cannot provide the direct evidence for the dimer model of TMPyP but can be interpreted reasonably in terms as that both TMPyP and TOPyP form the dimers in water even at very low concentrations while TAPP exists predominantly as its monomer.A dipole-induced dipole interaction seems to play an important role in the formation of the dimers and other molecular complexes of TMPyP and TOPyP.