92777-47-4Relevant academic research and scientific papers
PHOTOCHEMICAL REACTION OF 2-ALKENOYL-3,5-DIMETHYL-1,4-BENZOQUINONES WITH ALCOHOL
Maruyama, Kazuhiro,Iwamoto, Hidetoshi,Soga, Osamu,Takuwa, Akio
, p. 1343 - 1346 (1984)
Irradiation of 2-alkenoyl-3,5-dimethyl-1,4-benzoquinones in alcohol under nitrogen atmosphere afforded the two isomeric adducts: benzofuranone derivatives and novel alkenyl ether derivatives and novel alkenyl ether derivatives.The mechanism of formation o
Photoinduced Reductive Addition Reactions of 2-Alkenoyl-1,4-benzoquinones with Alcohols
Iwamoto, Hidetoshi
, p. 1507 - 1515 (2007/10/02)
Irradiation of 2-alkenoyl-3,5-dimethyl-1,4-benzoguinones 1 in alcohol under a nitrogen atmosphere afforded two isomeric adducts: benzofuranone derivatives 4 and alkenyl ether derivatives 5.The ratios of 4 to 5 depended both on the nature of the alkenoyl substituents and on the alcohols used as solvent.Irradiation of some quinones 1 dissolved in tert-butyl alcohol gave, however, 3-substituted chromone derivatives 13 as additional products.
