927902-91-8Relevant academic research and scientific papers
A facile Pd(0)-catalyzed regie- and stereoselective diamination of conjugated dienes and trienes
Du, Haifeng,Zhao, Baoguo,Shi, Yian
, p. 762 - 763 (2007)
This paper describes a novel diamination process using di-t-butyldiaziridinone as the nitrogen source and Pd(PPh3)4 as catalyst. A wide variety of conjugated dienes and trienes can be effectively diaminated in good yields with high r
Diamination of conjugated dienes and trienes catalyzed by N-heterocyclic carbene-Pd(0) complexes
Xu, Liang,Du, Haifeng,Shi, Yian
, p. 7038 - 7041 (2007)
(Chemical Equation Presented) This paper describes a diamination process using di-t-butyldiaziridinone as nitrogen source and N-heterocyclic carbene-Pd(0) complex as catalyst. A wide variety of conjugated dienes and trienes can be effectively diaminated i
A Pd(0)-catalyzed diamination of terminal olefins at allylic and homoallylic carbons via formal C-H activation under solvent-free conditions
Du, Haifeng,Yuan, Weicheng,Zhao, Baoguo,Shi, Yian
, p. 7496 - 7497 (2007)
This paper describes a novel diamination process of terminal olefins at allylic and homoallylic carbons via formal C-H activation using di-tert-butyldiaziridinone as nitrogen source and Pd(PPh3)4 as catalyst. A wide variety of termin
Cu(I)-catalyzed diamination of conjugated dienes. Complementary regioselectivity from two distinct mechanistic pathways involving Cu(II) and Cu(III) species
Zhao, Baoguo,Peng, Xingao,Zhu, Yingguang,Ramirez, Thomas A.,Cornwall, Richard G.,Shi, Yian
supporting information; experimental part, p. 20890 - 20900 (2012/02/04)
Conjugated dienes can be diaminated at the internal and/or terminal double bonds using Cu(I) as catalyst and N,N-di-t-butyldiaziridinone (1) as nitrogen source. The regioselectivity is highly dependent upon the choice of Cu(I) catalyst and the substituent
