92793-76-5Relevant academic research and scientific papers
Phosphorinanes as ligands for palladium-catalyzed cross-coupling chemistry
Brenstrum, Tim,Clattenburg, Julie,Britten, James,Zavorine, Serguei,Dyck, Jeff,Robertson, Alan J.,McNulty, James,Capretta, Alfredo
, p. 103 - 105 (2006)
(Chemical Equation Presented) Phosphorinanes are presented as a class of phosphine ligand suitable for organopalladium cross-coupling chemistry. Prepared via a direct double Michael addition of a monoalkyl- or arylphosphine to phorone followed by a Wolf-K
Access to 2′-substituted binaphthyl monoalcohols via complementary nickel-catalyzed kumada coupling reactions under mild conditions: Key role of a P,O ligand
Handa, Sachin,Mathota Arachchige, Yohan L. N.,Slaughter, Legrande M.
, p. 5694 - 5699 (2013/07/26)
Two complementary Kumada coupling methods for the conversion of monotriflated 1,1′-binaphthalene-2,2′-diol (BINOL) into 2′-substituted binaphthyl monoalcohols under mild conditions are reported. A protocol using NiCl2(dppe), in combination with
P-phenyl-2,2,6,6-tetramethylphosphorinan-4-ol: An air-stable p,o-type ligand for palladium-mediated cross-coupling reactions
Ullah, Ehsan,McNulty, James,Larichev, Vladimir,Robertson, Al J.
, p. 6824 - 6830 (2011/03/19)
A two-step entry to a chemically robust, hindered P,O-type phosphorinane-based ligand and its application toward Pd-mediated cross-coupling reactions of unactivated aryl chlorides is presented. A two-step entry to a chemically robust, hindered P,O-type phosphorinane-based ligand and its application toward Pd-mediated cross-coupling reactions of unactivated aryl chlorides is presented. Copyright
A novel P,O-type phosphorinane ligand for the Suzuki-Miyaura cross-coupling of aryl chlorides
Ullah, Ehsan,McNulty, James,Robertson, Al
body text, p. 5599 - 5601 (2011/02/22)
The Pd-mediated Suzuki-Miyaura cross-coupling of substituted and unsubstituted aryl chlorides with phosphorinane ligands was investigated uncovering an interesting ligand effect. The scope of the most effective 4-hydroxyl-substituted phosphorinane ligand in Suzuki cross-coupling with challenging aryl chlorides is described.
