928206-76-2Relevant academic research and scientific papers
Diastereo- and enantioselective synthesis of nitroso Diels-Alder-type bicycloketones using dienamine: Mechanistic insight into sequential nitroso aldol/Michael reaction and application for optically pure 1-amino-3,4-diol synthesis
Momiyama, Norie,Yamamoto, Yuhei,Yamamoto, Hisashi
, p. 1190 - 1195 (2007/10/03)
This article presents complete diastereo- and highly enantioselective synthesis of nitroso Diels-Alder-type bicycloketones using dienamine. With the hydrogen bonding of two hydroxyls in the bulky binaphthol 1c, high enantioselectivities and complete diast
