92844-11-6Relevant academic research and scientific papers
ENANTIOSELECTIVE SYNTHESIS OF THE α-HYDROXY-α-METHYL-β-HYDROXY UNITS VIA ASYMMETRIC ALDOL REACTION
Mukaiyama, Teruaki,Shiina, Isamu,Izumi, Jun,Kobayashi, Shu
, p. 719 - 724 (2007/10/02)
The α-hydroxy-α-methyl-β-hydroxy units are enantioselectively prepared by way of asymmetric aldol reactions between both achiral β,β-disubstituted silyl enolates and aldehydes. (-)-2-C-Methyl-D-threono-1,4-lactone is conveniently synthesized by using this
An Efficient Method for the Preparation of Chiral Synthons Starting from Racemic Compounds by Way of Asymmetric Synthesis
Kobayashi, Shu,Shiina, Isamu,Izumi, Jun,Mukaiyama, Teruaki
, p. 373 - 376 (2007/10/02)
Optically active α-alkoxy-α-methyl-β-hydroxy ester derivatives are prepared starting from racemic α-alkoxy propionic acid ester derivatives by way of asymmetric aldol reaction of the corresponding achiral intermediates. (-)-2-C-Methyl-D-threono-1,4-lacton
