92854-06-3

Basic information

• Product Name: 1,1-BIS-(4-CHLOROPHENYL)-BUTA-1,3-DIENE
• Synonyms: 1,1-BIS-(4-CHLOROPHENYL)-BUTA-1,3-DIENE
• CAS NO: 92854-06-3
• Molecular Formula: C₁₆H₁₂Cl₂
• Molecular Weight: 275.17248
• Mol File: 92854-06-3.mol
• Article Data: 7

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1,1-BIS-(4-CHLOROPHENYL)-BUTA-1,3-DIENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1-BIS-(4-CHLOROPHENYL)-BUTA-1,3-DIENE(92854-06-3)
• EPA Substance Registry System: 1,1-BIS-(4-CHLOROPHENYL)-BUTA-1,3-DIENE(92854-06-3)

Safety Data

• Hazardous Substances Data: 92854-06-3(Hazardous Substances Data)

Usage

General Description

1,1-Bis-(4-chlorophenyl)-buta-1,3-diene is a chemical compound with the molecular formula C16H12Cl2. It is a synthetic organic compound commonly known as disodium 1,1'-(4-chloro-1,2-phenylene)bis(1-phenyleth-3-ylidene)bis(phosphonate). 1,1-BIS-(4-CHLOROPHENYL)-BUTA-1,3-DIENE is commonly used as an intermediate in the synthesis of pharmaceuticals, agrochemicals, and other organic compounds. It is also used in the production of dyes and pigments. Additionally, this chemical has been studied for its potential application as an antiviral and antifungal agent. However, its use and handling must be conducted with caution due to its potential environmental and health hazards.

Upstream product

• 90-98-2 4,4'-Dichlorobenzophenone 
• 18925-10-5 allylzinc bromide 
• 106-95-6 allyl bromide 
• 106-39-8 bromochlorobenzene 
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• 214116-83-3 di(4-chlorophenyl)methylenecyclopropane 
• 288611-69-8 4-Dimethylamino-1,1-bis-<4-chlor-phenyl>-buten-(1) 
• 708967-53-7 1,1-bis-(4-chloro-phenyl)-4-dimethylamino-butan-1-ol 
• 1730-25-2 allylmagnesium bromide 

Downstream Products

• 6958-90-3 1,6-diphenylhexane-3,4-dione 
• 1556998-02-7 2-[2,2-bis(4-chlorophenyl)ethenyl]-6,6-dimethyl-2,3,6,7-tetrahydrobenzofuran-4(5H)-one 
• 1556997-75-1 2-[2,2-Bis(4-chlorophenyl)ethenyl]-3,5-dihydro-5-methylfuro[3,2-c]quinolin-4(2H)-one 

Relevant articles and documents

Neodymium-Promoted Highly Selective Carbon-Carbon Double Bond Formation of Ketones with Allyl Halides in the Presence of Diethyl Phosphite

The carbon-carbon double bond formation via neodymium-mediated Barbier-type reaction of ketones and allyl halides in the presence of diethyl phosphite is reported for the first time. The reaction is highly α-regioselective and was conveniently carried out under mild conditions in a one-pot fashion. From a synthetic point of view, a series of conjugated alkenes were obtained in moderate to good yields in this one-pot reaction with feasible reaction conditions.

Pd(0)-catalyzed cross-coupling of allyl halides with α-diazocarbonyl compounds or N-mesylhydrazones: Synthesis of 1,3-diene compounds

With palladium catalysis, allyl bromides or chlorides react with α-diazocarbonyl compounds or N-mesylhydrazones to afford 1,3-diene derivatives. The reaction represents a novel and efficient method for the synthesis of 1,3-butadiene derivatives. Mechanist

A novel ketone olefination via organozinc reagents in the presence of diphenyl phosphite

Carbonyl compounds react with organozinc reagents in the presence of diphenyl phosphite to give the corresponding olefins. A variety of 1,3-dienes and unsaturated esters were obtained in moderate to excellent yields under mild conditions. The Royal Society of Chemistry 2012.