928673-83-0Relevant academic research and scientific papers
Diastereoselective control of intramolecular aza-Michael reactions using achiral catalysts
Zhong, Cheng,Wang, Yikai,Hung, Alvin W.,Schreiber, Stuart L.,Young, Damian W.
, p. 5556 - 5559 (2011/12/05)
An intramolecular aza-Michael reaction with a Cbz carbamate and an enone is reported to result in 3,5-disubstituted nitrogen-containing heterocycles. Either cis or trans isomers were obtained selectively using chiral substrates and an achiral Pd (II) comp
Mild conditions for Pd-catalyzed carboamination of N-protected hex-4-enylamines and 1-, 3-, and 4-substituted pent-4-enylamines. Scope, limitations, and mechanism of pyrrolidine formation
Bertrand, Myra Beaudoin,Neukom, Joshua D.,Wolfe, John P.
supporting information; experimental part, p. 8851 - 8860 (2009/04/11)
(Chemical Equation Presented) The use of the weak base Cs 2CO3 in Pd-catalyzed carboamination reactions of N-protected γ-aminoalkenes with aryl bromides leads to greatly increased tolerance of functional groups and alkene substitutio
Mild conditions for the synthesis of functionalized pyrrolidines via Pd-catalyzed carboamination reactions
Bertrand, Myra Beaudoin,Leathen, Matthew L.,Wolfe, John P.
, p. 457 - 460 (2007/10/03)
The palladium-catalyzed carboamination of N-protected y-aminoalkenes with aryl bromides and triflates has been achieved under new, mild reaction conditions using the weak base Cs2CO3 in dioxane solvent. These reactions tolerate a wid
