929103-40-2Relevant articles and documents
Efficient and Practical Synthesis of Electron Transport Material and Its Key Intermediate
Zhao, Xiangdong,Li, Guijie,Zhu, Zhi-Qiang,Fang, Kun,Yang, Yuning,Li, Jian,She, Yuanbin
, p. 1675 - 1681 (2017)
An efficient and practical synthesis of 2,7-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)triphenylene 4 from two cheap commodity chemicals in five steps with a total yield of 48.6% was developed. This process had been successfully applied in the synthesis of electron transport material (ETM) BPyTP-2 in the gram scale with a total yield of 47.2%. This practical development of the key intermediate 4 opens a door in its further application in the synthesis of other triphenylene-based ETMs and host materials in the materials field.
Module-Patterned Polymerization towards Crystalline 2D sp2-Carbon Covalent Organic Framework Semiconductors
Jin, Enquan,Geng, Keyu,Fu, Shuai,Addicoat, Matthew A.,Zheng, Wenhao,Xie, Shuailei,Hu, Jun-Shan,Hou, Xudong,Wu, Xiao,Jiang, Qiuhong,Xu, Qing-Hua,Wang, Hai I.,Jiang, Donglin
supporting information, (2022/01/13)
Despite rapid progress over the past decade, most polycondensation systems even upon a small structural variation of the building units eventually result in amorphous polymers other than the desired crystalline covalent organic frameworks. This synthetic dilemma is a central and challenging issue of the field. Here we report a novel approach based on module-patterned polymerization to enable efficient and designed synthesis of crystalline porous polymeric frameworks. This strategy features a wide applicability to allow the use of various knots of different structures, enables polycondensation with diverse linkers, and develops a diversity of novel crystalline 2D polymers and frameworks, as demonstrated by using the C=C bond-formation polycondensation reaction. The new sp2-carbon frameworks are highly emissive and enable up-conversion luminescence, offer low band gap semiconductors with tunable band structures, and achieve ultrahigh charge mobilities close to theoretically predicted maxima.
Two-in-One Strategy for the Pd(II)-Catalyzed Tandem C-H Arylation/Decarboxylative Annulation Involved with Cyclic Diaryliodonium Salts
Hu, Tao,Xu, Kai,Ye, Zenghui,Zhu, Kai,Wu, Yanqi,Zhang, Fengzhi
supporting information, p. 7233 - 7237 (2019/10/02)
We report here a two-in-one strategy for the Pd(II)-catalyzed tandem C-H arylation/decarboxylative annulation between readily available cyclic diaryliodonium salts and benzoic acids. The carboxylic acid functionality can be used as both a directing group for the ortho-C-H arylation and the reactive group for the tandem decarboxylative annulation. By a step-economical double cross-coupling annulation procedure, the privileged triphenylene frameworks were efficiently constructed, which have potential applications in material chemistry.
The pyridyl group a substituent having a triphenylene ring compound having a structure and organic electroluminescent element
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, (2018/12/12)
Provided are: an organic compound that has excellent electron injection/transport performance properties, and serves as a material for a low-power-consumption organic electroluminescent element; and a low-power-consumption organic electroluminescent eleme
COMPOUND CONTAINING SUBSTITUTED TRIPHENYLE RING STRUCTURE, AND ORGANIC ELECTROLUMINESCENT ELEMENT
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, (2014/01/17)
An organic compound having an excellent electron injection and transport performance is provided as a material for a low-power-consumption organic electroluminescent device. A low-power-consumption organic electroluminescent device is also provided by using the compound. The compound is a compound of general formula (1) or (2) having a substituted bipyridyl and triphenylene ring structure. The organic electroluminescent device includes a pair of electrodes, and one or more organic layers sandwiched between the pair of electrodes, and uses the compound as constituent material of at least one of the organic layers.
NOVEL m-TERPHENYL COMPOUND AND ORGANIC LIGHT EMITTING DEVICE INCLUDING THE SAME
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, (2011/11/06)
An organic light emitting device which includes a m-terphenyl compound having a high T1 energy is provided. In addition, a novel m-terphenyl compound is provided.
BLUE ELECTROLUMINESCENT COMPOUNDS WITH HIGH EFFICIENCY AND DISPLAY DEVICE USING THE SAME
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Page/Page column 10-11, (2011/04/14)
The present invention relates to novel organic electroluminescent compounds and display devices comprising the same. The organic electroluminescent compounds according to the present invention exhibit high luminous efficiency and excellent life property, so that an OLED device having very good operation life can be prepared therefrom.
ELECTRON TRANSPORTING MATERIAL AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME
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Page/Page column 73-74, (2008/06/13)
A compound represented by the formula (1):wherein G represents a n-valent linker group; n represents an integer of 2 to 4; R1 to R4 independently represent a hydrogen, a univalent group or a free atomic valency binding to the group G; and R5 to R8 independently represent a hydrogen or a univalent group; provided that any one of R1 to R4 is a free atomic valency binding to the group G, and n's 2,3'-bipyridyl groups may be the same as or different from one another. The compound is useful as an electron transporting material for an organic electroluminescent device. An organic electroluminescent device having the compound in the electron transporting layer shows a long operating life and a low driving voltage.