929208-90-2

Basic information

• Product Name: (2S,3R,4S)-1-benzyl-2-[(benzyloxy)methyl]-3,4-(isopropylidenedioxy)pyrrolidine
• Synonyms: (2S,3R,4S)-1-benzyl-2-[(benzyloxy)methyl]-3,4-(isopropylidenedioxy)pyrrolidine
• CAS NO: 929208-90-2
• Molecular Weight: 353.461
• Mol File: 929208-90-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S,3R,4S)-1-benzyl-2-[(benzyloxy)methyl]-3,4-(isopropylidenedioxy)pyrrolidine(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3R,4S)-1-benzyl-2-[(benzyloxy)methyl]-3,4-(isopropylidenedioxy)pyrrolidine(929208-90-2)
• EPA Substance Registry System: (2S,3R,4S)-1-benzyl-2-[(benzyloxy)methyl]-3,4-(isopropylidenedioxy)pyrrolidine(929208-90-2)

Safety Data

• Hazardous Substances Data: 929208-90-2(Hazardous Substances Data)

Upstream product

• 5336-08-3 D-Ribono-1,4-lactone 
• 100-39-0 benzyl bromide 
• 85846-80-6 5-O-benzyl-2,3-O-isopropylidene-D-ribono-1,4-lactone 
• 929208-88-8 (2R,3R,4R)-N-benzyl-5-benzyloxy-2,3-isopropylidenedioxy-4-hydroxypentanamide 
• 30725-00-9 2,3-O-isopropylidene-D-ribonic-γ-lactone 

Relevant articles and documents

Synthesis of alkaloid analogues from β-amino alcohols by β-fragmentation of primary alkoxyl radicals

The fragmentation of primary alkoxyl radicals is usually a minor process with respect to hydrogen abstraction and other competing reactions. However, when β-amino alcohols were used as substrates, the scission proceeded in good to excellent yields and no side reactions were observed. The fragmentation can be coupled with an allylation or alkylation reaction, to give alkaloid analogues and functionalized nitrogen heterocycles. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.