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92922-07-1

{Rh(SC6H5)(P(C6H5)3)2}2 is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 92922-07-1 Structure

  • Basic information

    1. Product Name: {Rh(SC6H5)(P(C6H5)3)2}2
    2. Synonyms: {Rh(SC6H5)(P(C6H5)3)2}2
    3. CAS NO:92922-07-1
    4. Molecular Formula:
    5. Molecular Weight: 1473.32
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 92922-07-1.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: {Rh(SC6H5)(P(C6H5)3)2}2(CAS DataBase Reference)
    10. NIST Chemistry Reference: {Rh(SC6H5)(P(C6H5)3)2}2(92922-07-1)
    11. EPA Substance Registry System: {Rh(SC6H5)(P(C6H5)3)2}2(92922-07-1)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 92922-07-1(Hazardous Substances Data)

92922-07-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 92922-07-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,2,9,2 and 2 respectively; the second part has 2 digits, 0 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 92922-07:
(7*9)+(6*2)+(5*9)+(4*2)+(3*2)+(2*0)+(1*7)=141
141 % 10 = 1
So 92922-07-1 is a valid CAS Registry Number.

92922-07-1Downstream Products

92922-07-1Relevant articles and documents

Cleavage of C-S bond in allylic aryl sulfides promoted by rhodium hydride complex: Reaction mechanisms of allyl-sulfur bond fission

Osakada, Kohtaro,Matsumoto, Keizo,Yamamoto, Takakazu,Yamamoto, Akio

, p. 857 - 862 (2008/10/08)

Reactions of allylic aryl sulfides with RhH(PPH3)4 cause cleavage of allylic sulfur bond to afford rhodium thiolato complexes [Rh(μ-SAr)(PPh3)2]2 and olefins under mild conditions. Distributions of olefinic products in the reactions of sulfides having alkyl substituents on the allyl part such as 3-(phenylthio)-1-butene and 1-(phenylthio)-2-butene indicate that selective rearrangement of C=C bond occurs. The reaction of 3-(phenylthio)propene with RhD(P(C6D5)3)4 gives propylene as a mixture of C3H6, C3H5D, C3H4D2, and C3H3D3 with recovery of partly deuterated 3-(phenylthio)propene, suggesting hydrogen exchange between 3-(phenylthio)propene and rhodium hydride complex prior to the C-S bond cleavage. New rhodium thiolato complexes obtained from these reactions are characterized by IR and/or NMR spectroscopy, elemental analysis, and their chemical reactions.

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