92945-38-5

Basic information

• Product Name: Cyclohexanone, 4,4-dimethyl-3-(1-oxopropyl)-
• CAS NO: 92945-38-5
• Molecular Formula: C11H18O2
• Molecular Weight: 182.263
• Mol File: 92945-38-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 4,4-dimethyl-3-(1-oxopropyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 4,4-dimethyl-3-(1-oxopropyl)-(92945-38-5)
• EPA Substance Registry System: Cyclohexanone, 4,4-dimethyl-3-(1-oxopropyl)-(92945-38-5)

Safety Data

• Hazardous Substances Data: 92945-38-5(Hazardous Substances Data)

Upstream product

• 1073-13-8 4,4-dimethylcyclohexenone 
• 201230-82-2 carbon monoxide 
• 557-20-0 diethylzinc 
• 56830-41-2 2,2-dimethyl-5-oxo-cyclohexanecarbonitrile 
• 108-03-2 1-Nitropropane 
• 592-02-9 diethylcadmium 
• 137600-97-6 2,2-Dimethyl-5-oxo-cyclohexanecarbonyl chloride 
• 925-90-6 ethylmagnesium bromide 
• 137600-87-4 3-cyano-4,4-dimethylcyclohexanone ethylene ketal 

Relevant articles and documents

Pd-catalyzed carbonylative conjugate addition of dialkylzinc reagents to unsaturated carbonyls

The Pd-catalyzed addition of organozinc reagents to unsaturated carbonyls in the presence of carbon monoxide provides 1,4-diketones in good yield. The reaction was studied with a number of substituted cyclic and acyclic ketones as well as α,β-unsaturated aldehydes.

Ueber die Bildung von Dihydro-1,2-oxazin-N-oxiden durch intramolekulare Addition eines Nitronat-Anions an eine Carbonylgruppe

Highly substituted 4-keto-1-nitroalkanes cyclize under basic conditions to dihydro-1,2-oxazine N-oxides.These N-oxides are thermally unstable and decompose to 1,4-diketones.BF3 catalyzes a similar decomposition, but probably via a different mechanism.