92945-44-3

Upstream product

• 1073-13-8 4,4-dimethylcyclohexenone 
• 75-52-5 nitromethane 
• 79-24-3 Nitroethane 

Downstream Products

• 137600-96-5 3-Acetyl-2,6-dibromo-4,4-dimethyl-cyclohexanone 
• 137600-84-1 3-acetyl-4,4-dimethylcyclohex-2-enone 
• 127701-69-3 3-acetyl-4,4-dimethylcyclohexa-2,5-dienone 
• 92945-36-3 (2,2-dimethyl-5-oxocyclohexyl)methylketon 

Relevant academic research and scientific papers

Ueber die Bildung von Dihydro-1,2-oxazin-N-oxiden durch intramolekulare Addition eines Nitronat-Anions an eine Carbonylgruppe

Highly substituted 4-keto-1-nitroalkanes cyclize under basic conditions to dihydro-1,2-oxazine N-oxides.These N-oxides are thermally unstable and decompose to 1,4-diketones.BF3 catalyzes a similar decomposition, but probably via a different mechanism.

Asymmetric multifunctional organocatalytic Michael addition of nitroalkanes to α,β-unsaturated ketones

Cinchona alkaloid derived primary amine thioureas organocatalyzed Michael addition of nitroalkanes to enones in good yield and up to 98% ee and offered a new way to construct quaternary stereocenters from enones and nitroalkanes. The Royal Society of Chem