Ueber die Bildung von Dihydro-1,2-oxazin-N-oxiden durch intramolekulare Addition eines Nitronat-Anions an eine Carbonylgruppe

DOI: 10.1002/hlca.19840670320

Source and publish data:

Helvetica Chimica Acta p. 789 - 795 (1984)

Update date:2022-08-05

Topics:

Authors:

Kienzle, Frank

Fellmann, Jean-Yves

Stadlwieser, Josef

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/hlca.19840670320

Highly substituted 4-keto-1-nitroalkanes cyclize under basic conditions to dihydro-1,2-oxazine N-oxides.These N-oxides are thermally unstable and decompose to 1,4-diketones.BF3 catalyzes a similar decomposition, but probably via a different mechanism.

Full text of DOI:10.1002/hlca.19840670320

Products guided by the article

Product name:Cyclohexanone, 4,4-dimethyl-3-(1-nitroethyl)-

Cas No:92945-44-3

R&D Labs maybe for 92945-44-3

JIANGXI AIFEIMU TECHNOLOGY CO.，LTD

Contact:+86-570-6040289

Address:FINECHEMICAL PARK,ZIBU TOWN,WANNIAN COUNTY,JIANGXI PROV.,CHINA,ZIP
Anhui Eapearl Chemical Co., Ltd.

Contact:86-562-5858458

Address:358 South Huaihe Road
Nanjing Fayekong Chemcial Co.,Ltd(expird)

Contact:86-25-58813444

Address:Rm 1503, Unit 1, Building 5, Zijinnanyuan, Nanjing, Jiangsu, China
Ji'nan Orgachem Pharmaceutical Co.,Ltd

Contact:+86-531-82687810

Address:Jinan
Zhejiang Haizhou Pharmaceutical Co., Ltd.

website:https://www.haizhoupharma.com/

Contact:+86-576-88221016

Address:No. 19, Donghai 5th Avenue, Yanhai Industrial Zone, Linhai, Zhejiang, China

Relevant to this article

BORON TRIFLUORIDE CATALYSED REACTIONS OF 2,2,2-TRICHLOROETHYL 6-DIAZOPENICILLANATE WITH AROMATIC ALDEHYDES: REARRANGEMENTS VIA PENAM C(5)-C(6) BOND CLEAVAGE.

Doi:10.1016/S0040-4039(01)81325-3
(1984)
Doi:10.1021/ja01150a515
(1951)
Phenacylsulfonylacetic esters - Source for thiadiazoles, triazoles and oxadiazoles

Doi:10.1002/jhet.5570440116
(2007)
Isophthalic Acid-Based HDAC Inhibitors as Potent Inhibitors of HDAC8 from Schistosoma mansoni

Doi:10.1002/ardp.201700096
(2017)
Signal-amplifying conjugated polymer-DNA hybrid chips

Doi:10.1002/anie.200700419
(2007)
Ligand substitution processes in tetranuclear carbonyl clusters. 9. Reactions of Co₄(CO)₉(tripod), tripod = HC(PPh₂)₃, and its derivatives

Doi:10.1021/om00120a016
(1985)

Article Doi