929557-06-2Relevant academic research and scientific papers
Novel ruthenium-catalyst for hydroesterification of olefins with formates
Profir, Irina,Beller, Matthias,Fleischer, Ivana
supporting information, p. 6972 - 6976 (2014/10/15)
An alternative ruthenium-based catalyst for the hydroesterification of olefins with formates is reported. The good activity of our system is ensured by the use of a bidentate P,N-ligand and ruthenium dodecacarbonyl. A range of formates can be used for selective alkoxycarbonylation of aromatic olefins. In addition, the synthesis of selected aliphatic esters is realized. The proposed active ruthenium complex has been isolated and characterized. This journal is the Partner Organisations 2014.
Indirect ortho functionalization of substituted toluenes through ortho olefination of N,N-dimethylbenzylamines tuned by the acidity of reaction conditions
Cai, Guixin,Fu, Ye,Li, Yizhou,Wan, Xiaobing,Shi, Zhangjie
, p. 7666 - 7673 (2008/02/09)
Highly regioselective olefination of substituted N,N-dimethylbenzylamines was developed by tuning the acidity of reaction conditions based on analysis of their features. The ortho-functionalized N,N-dimethylbenzylamines were further transformed into 3-(2′
