92960-67-3Relevant articles and documents
Metal-free 5-exo-dig cyclization of propargyl urea using TBAF
Huguenot, Florent,Delalande, Clémence,Vidal, Michel
, p. 4632 - 4635 (2014)
We present the first results of the intramolecular cyclization of propargyl ureas catalyzed by TBAF. Depending on the substituents close to the triple bond, imidazolone or methylene-imidazolidinone was obtained. The dual activation of the triple bond by interaction with TBAF via the cation-π is thought to be responsible.