92964-20-0Relevant academic research and scientific papers
Late stage Fe(CO)5 promoted double bond migration: Total synthesis of limazepines C and D
Sakaine, Guna,Smits, Gints,Zemribo, Ronalds
, p. 4767 - 4769 (2015)
The first total syntheses of limazepines C and D were accomplished from inexpensive and readily available starting materials using an iron pentacarbonyl promoted allylamide-enamide double bond migration as a key step. The obtained limazepine C was found to be unstable and undergoes oxidation to limazepine D.
