929706-64-9Relevant academic research and scientific papers
A gold(III)-catalyzed double Wacker-type reaction of 1,1-diethynyl acetate
Kato, Keisuke,Teraguchi, Ryuhei,Kusakabe, Taichi,Motodate, Satoshi,Yamamura, Shigeo,Mochida, Tomoyuki,Akita, Hiroyuki
, p. 63 - 66 (2007)
Treatment of 1,1-diethynyl acetates in the presence of Au or Pt catalyst (5 mol%) in methanol at 60 °C for 20-48 hours gave γ-ketoesters and lactones in 40-54% and 19-39% yields, respectively. An oxygen atom is introduced to the first acetylene moiety in
