92974-02-2Relevant academic research and scientific papers
Aliphatic diazo compounds. XIV. The synthesis of 7-substituted 3-diazo-2-norbornanones and the infrared and proton and carbon-13 nuclear magnetic resonance spectra of these diazo ketones and their precursors
Yates, Peter,Kronis, John David
, p. 1751 - 1766 (2007/10/02)
syn and anti-7-Isopropyl-2-norbornanone (5 and 6) were prepared by catalitic hydrogenation of 7-isopropylidene-2-norbornanone; syn and anti-7-benzhydryl-2-norbornane (9 and 10) were prepared in analogous fashion.Ketones 5 and 6 and syn- and anti-7-tert-bu
THE ACID INDUCED DECOMPOSITION OF 7-SUBSTITUTED 3-DIAZO-2-NORBORNANONES.THE STRUCTURES OF THE PRODUCTS AND THEIR DISTRIBUTION
Yates, Peter,Kronis, John D.
, p. 2419 - 2422 (2007/10/02)
Introduction of a syn-7 isopropyl or t-butyl substituent in 3-diazo-2-norbornanone results in both endo and exo protonation in aqueous acid and a marked decrease in α-ketol and increase in tricyclanone formation.
