92976-75-5Relevant academic research and scientific papers
Fine regioselective tuning in the oxidation of sec,sec 1,2-diols by dimethyldioxirane
Bovicelli, Paolo,Sanetti, Anna,Lupattelli, Paolo
, p. 10969 - 10978 (2007/10/03)
Non-symmetric sec,sec 1,2-diols and their o-isopropylidene derivatives undergo a regioselective oxidation by dimethyldioxirane depending on the electronic effects of the substituents. These results support previous views about the concerted O-insertion mechanism via a polar transition state.
REARRANGEMENT OF α-ACYLOXYACETATES INTO 2-HYDROXY-3-KETOESTERS
Lee, S. D.,Chan, T. H.,Kwon, K. S.
, p. 3399 - 3402 (2007/10/02)
α-Acyloxyacetates rearrange under LDA conditions to give 2-hydroxy-3-ketoesters.The corresponding trimethylsilyl- or acetyl derivatives can be obtained by quenching the reaction mixture with Me3SiCl or Ac2O.
