92977-89-4Relevant academic research and scientific papers
REGIO- AND STEREOCHEMISTRY OF THE INTRAMOLECULAR PHOTOPRODUCTS FROM TWO RELATED VINYLOGOUS IMIDES
Swindell, Charles S.,deSolms, S. Jane,Springer, James P.
, p. 3797 - 3800 (1984)
The regio- and stereochemistry of the intramolecular photoproducts from two related vinylogous imides have been determined with the aid of X-ray crystallography; their chemistry and a mechanistic rationale of their formation are presented.
A Route for the Construction of the Taxane BC Substructure
Swindell, Charles S.,Patel, Bomi P.,deSolms, S. Jane
, p. 2346 - 2355 (2007/10/02)
A stereospecific synthesis of taxane BC intermediate 6 from photoproduct 17 is described.Vinylogous imides 12-14 were prepared in four steps from cyclohexanone cyanohydrin and dimedone.Their irradiation led to respective photoproducts 15-21.Unequivocal id
