69089-07-2

Upstream product

• 1855-63-6 cyclohex-1-enecarbonitrile 
• 32917-19-4 cyclohex-1-en-1-ylmethylamine 
• 126-81-8 dimedone 

Downstream Products

• 122048-92-4 6-Amino-4,4-dimethyl-2'-methylene-bicyclohexyl-6-en-2-one 
• 122048-93-5 (1S,10R)-6,6-Dimethyl-3-aza-tricyclo[8.4.0.0^1,4]tetradec-3-en-8-one 
• 69089-06-1 N-Cyclohex-1-enylmethyl-N-(5,5-dimethyl-3-oxo-cyclohex-1-enyl)-acetamide 
• 92977-89-4 N-Cyclohex-1-enylmethyl-N-(5,5-dimethyl-3-oxo-cyclohex-1-enyl)-formamide 
• 108343-97-1 (2,2,2-trichloroethoxy)carbonyl imide 
• 122048-94-6 4,4-Dimethyl-6-methylamino-2'-methylene-bicyclohexyl-6-en-2-one 
• 108344-04-3 N-(2'-Hydroxy-4',4'-dimethyl-6'-oxo-bicyclohexyl-1-ylmethyl)-acetamide 
• 108344-02-1 4,4,1'-Trimethyl-bicyclohexyl-2,6-dione 
• 122068-64-8 3-<(cyclohexenylmethyl)methylamino>-5,5-dimethyl-2-cyclohexen-1-one 

Relevant academic research and scientific papers

Photo-Aza-Claisen Rearrangements of Cyclic Enaminones

Cyclic enaminoes 1-7 were prepared and photolyzed.Compounds 1-4 reacted as expected to provide aza-De Mayo products 10 and 11, whereas 5 provided enaminone 12 in a novel photo-aza-Claisen rearrangement.Compounds 6 and 7 gave photo-aza-Claisen products 13 and 16, respectively, along with aza-De Mayo product 15 and 2 + 2 cycloaddition product 17, respectively.