929803-76-9

Upstream product

• 98-09-9 benzenesulfonyl chloride 
• 1207966-49-1 3-Hydroxymethyl-1-phenylsulfonyl-1,2,5,6-tetrahydropyridine 
• 300-08-3 arecoline hydrobromide 
• 929803-75-8 methyl 1-benzenesulfonyl-1,2,5,6-tetrahydropyridine-3-carboxylate 

Downstream Products

• 929803-83-8 (4aS,8S,8aS)-N-allyl-N-[2-benzenesulfonyl-6-(tert-butyldimethylsiloxy)-8a-formyl-1,2,3,4,4a,5,8,8a-octahydroisoquinolin-8-yl]chloroacetamide 
• 929803-85-0 3-[2-benzenesulfonyl-6-(tert-butyl-dimethyl-silanyloxy)-8-(2-chloro-acetylamino)-2,3,4,4a,5,8-hexahydro-1H-isoquinolin-8a-yl]-acrylic acid ethyl ester 
• 929803-87-2 C₂₄H₃₁ClN₂O₇S 
• 929803-84-9 N-[2-benzenesulfonyl-6-(tert-butyl-dimethyl-silanyloxy)-8a-formyl-1,2,3,4,4a,5,8,8a-octahydro-isoquinolin-8-yl]-2-chloro-acetamide 

Relevant academic research and scientific papers

Asymmetric synthesis of hydroisoquinoline derivatives, a key intermediate for manzamine synthesis, by diels-alder reaction using 4-amino-2-siloxybutadiene

A novel method for the synthesisof chiral hydroisoquinolines by asymmetricDiels-Alder reaction of nitrogen-containing dienophiles and suitably protected aminosiloxybutadienes has been developed.

Synthetic study of manzamine B: synthesis of the tricyclic central core by an asymmetric Diels-Alder and RCM strategy

Tricyclic core of manzamine B was successfully synthesized through asymmetric Diels-Alder reaction and RCM strategy. Cr-salen-F complex was found to be the most effective catalyst in DA reaction of aminodienes with heterocyclic dienophiles to give up to 9