92982-38-2Relevant articles and documents
Deoxofluorination reactions using N,N-disubstituted aminodifluorosulfinium tetrafluoroborate salts
Mahé, Olivier,L'Heureux, Alexandre,Couturier, Michel,Bennett, Christopher,Clayton, Simon,Tovell, David,Beaulieu, Francis,Paquin, Jean-Fran?ois
, p. 57 - 60 (2013/11/06)
The synthesis of N,N-disubstituted aminodifluorosulfinium tetrafluoroborate salts is reported, and their behavior as deoxofluorinating agent was evaluated. The deoxofluorination reactions were performed using a primary alcohol, a secondary alcohol and a ketone. Results show that subtle modification of the structure of the reagents can noticeably affect the reactivity and the selectivity in deoxofluorination reactions.
Diborane(4) Molecules with Boron Atoms with Different Coordination Number
Haubold, Wolfgang,Hrebicek, Johann,Sawitzki, Gisela
, p. 1027 - 1031 (2007/10/02)
Molecules with directly bonded boron atoms with different coordination numbers (10, 11, 12 and 13) can be prepared from suitable bifunctional bases like 6, 7, 8 or 9 and Cl2B-BCl2 (1) in an appropriate solvent at high dilution.Properties and spectroscopic data - including 1J(11B-11B) - are described.The molecular structure of 10 was investigated by means of an X-ray structure analysis. - Keywords: Diborane(4) Molecules, Bifunctional Bases, Synthesis, X-ray