92989-85-0Relevant academic research and scientific papers
REARRANGEMENT OF α-ACYLOXYACETATES INTO 2-HYDROXY-3-KETOESTERS
Lee, S. D.,Chan, T. H.,Kwon, K. S.
, p. 3399 - 3402 (1984)
α-Acyloxyacetates rearrange under LDA conditions to give 2-hydroxy-3-ketoesters.The corresponding trimethylsilyl- or acetyl derivatives can be obtained by quenching the reaction mixture with Me3SiCl or Ac2O.
